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All Videos in the DUI Video Collection
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DUI Videos Chemical Interferent
This is a collection of videos of experiments conducted relating to the reliability of evidentiary and other breath testing instruments including the Intoxilyzer 5000 and the Intoxilyzer 8000. This group of videos deals with the effects of chemical interferents such as Limonene or D-Limonene (Intoxilyzer 5000) and Diethyl Ether (Intoxilyzer 8000). Please don't confuse the term "interferent" with the term "interference" (as in radio frequency interference). This set of videos deals with chemical interferents which mimic ethyl alcohol. The approved instruments we use in Ontario, Canada apply Infra Red spectrum analysis (IR). The instrument hunts for the IR fingerprint for ethyl alcohol and then quantifies that result. But what happens if another substance is present in the breath chamber (from either the subject's breath or the environment of the breath room) that has a similar IR fingerprint to ethyl alcohol, from the perspective of that particular type or kind of approved instrument? Students and lawyers should study IR spectroscopy (or obtain expert advice) to understand how the Lambert-Beer law (Beer-Lambert law) only works in an Ontario approved instrument for one co-efficient (the one for alcohol). Students and lawyers need to know that the law only works for monochromatic light. The Ontario Intoxilyzer 8000C has an IR light filter of unknown (to Canadian forensic scientists) but probably wide bandwidth. If you surprise an Ontario Intoxilyzer with an environmental or body presentation of a chemical interferent, not-contemplated by the design of the instrument, you may receive a false or exaggerated result. Breath technicians and qualified technicians must follow strict protocols to exclude the possibility of an interferent in the breath room or on the breath of the subject. Defence lawyers MUST interview their clients as to workplace and hobby exposure to Ethyl Ether and Di-Ethyl Ether (e.g. diesel mechanic or engine hobbyist). Although Bill C-46 changes the law to exclude defences based on factual innocence, there probably is still a section 320.31(1) defence in these cases by attacking the reliability of the air blank system check and the system calibration check.
Defence lawyers need to be aware that there are serious limitations in the Ontario Intoxilyzer 8000C Training Aid respecting the reliability of IR analysis.
Some of the videos in this collection deal with false chemical "interferent" messages triggered by radio frequency interference (RFI). A chemical "interferent" flag may therefore be an indication that RFI is present in the breath room environment, though not detected by the instrument as "RFI".
Limonene or D-Limonene in the breath room can also result in high cal. checks resulting in a possible section 320.31(1) defence i.e. the system calibration tests are not reliable.
Ordinary bread may act as an interferent.
An interferent may raise or lower the setting of zero for instrument purposes resulting in changes to the ambient fail threshold - a potential section 320.31(1) air blank system defence.
You can find more information about chemical interferent bias:
DUIDictionary page "Interferent (in the context of the Intoxilyzer 8000C)"
DUIDictionary page "Interferent (in the context of the Intoxilyzer)"
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Read Blog Entries on System Blank Test
Lawyers, law students, forensic science students, and experts need to learn all they can about:
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How IR measuring instruments work
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Retain a chemistry professor and study a university text book
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How reliability of system blank tests and system calibration checks on IR instruments may be compromised by unusual subject body and environmental factors not contemplated by the design of the instrument
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How zero is set on an IR instrument
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What is an "ambient fail"
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What is a "purge fail" (not well understood by experts in Canada)
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What alcohol, interferents, or electronic noise are "masked" during an air blank/system blank test
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Ambient fail thresholds (not well understood by experts in Canada)
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Changes in ambient thresholds (in a matter of seconds)
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Cal. check/system calibration checks in the context of earlier ambient fails
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How alcohol can be made to disappear
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Specificity for ethyl alcohol and bandwidths of IR filters (not well understood by experts in Canada)
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Relevance of the audit trail for the approved instrument
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Relevance of the firmware/software that permits the instrument to work and sets thresholds, limits, challenges, and error messages
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ethyl alcohol analysis
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chemical interferent analysis
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ambient fail analysis
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cal. check system
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Video 08
Limonene24 - Low and High Cal. Checks - Lowering 0 - Contamination of Cal Checks
Intoxilyzer 5000 in need of maintenance. 100 alcohol standard at 34 C. Exposure to mixture of room temperature 50 alcohol standard and GOJO containing limonene bubbled into breath tube during air blanks plus GOJO on hands near flask air entry. After initial AMBIENT FAIL ACACA cal. checks now reading as low as 62 mg/100mls or even lower if INTERFERENT flag at 24 mgs/100mls. 0 has been raised by ethanol and limonene during air blanks far above 20 mg/100 mls threshold. In the process GOJO/limonene has either contaminated sample chamber, tubing, simulator or 100 alcohol standard or instrument's interferent add/subtract circuitry has been affected ultimately result in in 145 cal. check and 144 cal. check when room air used as ambient. Quaere: does contamination of an instrument and accesory equipment by an ambient interferent necessitate a change to the alcohol standard? Is it therefore necessary that the police log and the Crown disclose every "INTERFERENT" error (cards and COBRA/ADAMS) since the last solution change and prior to the subject test so that the defence will have full notice that the alcohol standard may have been unreliable? Intoxilyzer® is a registered trademark of CMI, Inc. The Intoxilyzer® 5000C is an "approved instrument" in Canada.
Video 09
Limonene30 - Low & High Cal. Checks Caused by Limonene
Intoxilyzer 5000 in need of maintenance. Experiments with GOJO hand cleaner containing limonene partially dissolved in cold 50 mg/100mls alcohol standard bubbled into breath tube during some air blanks. Effects on cal. checks with 200 alcohol standard. Sometimes but not always "Interferent" flag. Cal. checks far below and far above acceptable. Simulator/tubing/Intoxilyzer reliability compromised because cal. checks no longer reliable. Intoxilyzer® is a registered trademark of CMI, Inc. The Intoxilyzer® 5000C is an "approved instrument" in Canada.
Video 10
Limonene31 - High Cal. Checks Caused by Limonene
Intoxilyzer 5000 in need of maintenance. 100 alcohol standard at 34C. Note high cal. checks on ACACA and ACABA sequences. Calibration check system (sample chamber, interferent detect/subtract/add circuitry, tubing, simulator, or standard) has been compromised by previous experiments bubbIing mixture of cold 50 mg/100mls standard and GOJO containing limonene. Quaere: Once there has been any indication of an "Interferent" should the alcohol standard be changed? Should any "Interferent" flag since last alcohol standard change be disclosed to the defence since the alcohol standard may not be reliable? Intoxilyzer® is a registered trademark of CMI, Inc. The Intoxilyzer® 5000C is an "approved instrument" in Canada.
Video 11
Limonene25 - High Cal. Checks - Limonene
Intoxilyzer 5000 in need of maintenance. 100 alcohol standard at 34 C. Prior exposure to mixture of room temperature 50 alcohol standard and GOJO containing limonene bubbled into breath tube during air blanks plus GOJO on hands near flask air entry. ACACA cal. checks now reading as high as 134 mg/100mls. GOJO/limonene has either contaminated sample chamber, tubing, simulator or 100 alcohol standard or instrument's interferent add/subtract circuitry has been affected. Quaere: does contamination of an instrument and accesory equipment by an ambient interferent necessitate a change to the alcohol standard? Is it therefore necessary that the police log and the Crown disclose every "INTERFERENT" error (cards and COBRA/ADAMS) since the last solution change and prior to the subject test so that the defence will have full notice that the alcohol standard may have been unreliable?
Video 15
Limonene1 Cal. Checks 103, 81, 96, 85, 111, 105
Experiment to explore the effects of a hand cleaner such as GOJO containing limonene in the ambient air respecting reliability of the alcohol standard. 100 SAS in simulator at 34.0C. Operator runs ACACA mode. Cal. check drops from 103 to 81, 96, 85 when hand cleaner in air near breath tube on prior air blank and then returns to 111, 105. Note that 111 is outside of acceptable range. It appears that ambient hand cleaner in the breath room can reduce an apparent cal. check by 20 mg/100mls. Although the breath test result itself may be reduced, the reliability of the simulator/alcohol standard has been compromised and so the breath test itself is not reliable. If the instrument is, for example, reading 11 mgs/100 mls too high and the problem is not with the simulator (note the 111 cal. check), then this inaccuracy may be masked. Cal. checks could be in the normal 90 to 110 mgs/100mls range only because the cal. check reliability was compromised by the ambient limonene and the instrument's response thereto.
Video 16
ProcessorErrors 0030d Ambient Threshold Varies with Ambient Conditions
Main simulator has 100 SAS at 34.0C. This video is a sequel to two longer videos. Experiment using cold extra simulators at 40 mgs/100mls and 100 mgs/100mls gradually warmed to simulate slow changes in ambient ethanol in room air. Instrument does not trigger "Ambient Fail" because the change is gradual. The results of this experiment show why it is very important for the operator to control breath room ambient conditions and pay close attention to any indications of bizarre ambient conditions. Those indications may include strange cal. checks, ambient fail messages, and others in the weeks before and after the subject tests. In order to make full answer and defence respecting the issue of instrument reliability the defence needs full disclosure of conditions that affect the SAS reliability including expiry, stability, temperature, AND AMBIENT CONDITIONS IN THE BREATH ROOM. Please note that the need for such full disclosure is even more important if ambient conditions potentially include ethanol PLUS INTERFERENTS such as limonene.
Video 52
Cell Phone RFI Error Interferent 64 Series
This is an example of a false Error Message. The instrument indicates "Interferent" i.e. a chemical interferent when the cause is radio frequency interference (RFI). Error messages are not always reliable to identify the correct error.
ACACA calibration checks using 100 solution, first cal. check 102, second cal. check indicates "Interferent" then 106 when exposed to cell phone RFI